Note: We are displaying rounded intermediate values for practical purposes. However, the calculations are made using the unrounded values.
(a) The quantity of heat transferred is given by the equation
Q = nCVΔT
where
n is the number of moles of the gas,
ΔT is the change in temperature of the gas, and
CV
is the molar specific heat at constant volume.
Substitute the given values to get
Q1 = (2.50 mol)(27.0 J/mol)(465 K − 252 K) = 1.44 ✕ 104 J.
(b) Let
Eint
represent the internal energy,
Q the net heat transferred into the system and
W =
− | PΔV |
 |
|
the net work done on the system at constant pressure. Then the first law of thermodynamics can be written as
Since the volume of the gas remains constant, the work done on the gas is zero. Therefore, we have
ΔEint = Q1 = 1.44 ✕ 104 J.
(c) The quantity of heat transferred is given by the equation
Q = nCPΔT
where
n is the number of moles of the gas,
ΔT is the change in temperature of the gas, and
CP
is the molar specific heat at constant pressure.
Substitute the given values to get
Q2 = (2.50 mol)(35.4 J/mol)(465 K − 252 K) = 1.89 ✕ 104 J.
Note that this quantity is greater than that in part (a). This is because some of the heat input goes into increasing the internal energy of the gas, and some goes into increasing the volume of the gas at a constant pressure (which means work is done by the gas on its surroundings as it heats up).
(d)
ΔEint
is the same for the constant volume and constant pressure processes since the temperature change is the same.
Therefore
ΔEint = 1.44 ✕ 104 J.
We use
ΔEint = Q + W
to find the work done on the gas.
W | = | ΔEint − Q2 |
| = | 1.44 ✕ 104 J − 1.89 ✕ 104 J |
| = | −4.45 ✕ 103 J |
Alternatively, we can calculate work directly from the temperature change. Because the work on the gas is at a constant pressure,
W =
− | P dV |
 |
|
=
−PΔV =
−(
PVf − PVi)
For an ideal gas, we can substitute
PV = nRT
into the above and obtain
W | = | −nR(Tf − Ti) |
| = | −(2.50 mol)8.314 (465 K − 252 K) |
| = | −4.43 ✕ 103 J |
The work done on the gas is negative, because the volume of the gas is increasing. (The work done by the gas on the surroundings is the opposite sign of this result, and so would be positive in this case.)